This is the Venomized Phoenix cover by Francesco Mattina, an exclusive variant for Unknown Comics, for Jean Grey #1 out this month. It features a Dark Phoenix who has been taken over by the Venom symbiote, as part of a series of promotional Venom variant covers alongside the release of Venom #150.
And here is a Sideshow print of Dark Pheonix by Ian MacDonald from a wee while ago.
Separated At Birth: Francesco Mattina Venom and Ian MacDonald Phoenix
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